Effects of Electric Fields on Structure and Reactivity
Gebundenes Buch

Effects of Electric Fields on Structure and Reactivity

New Horizons in Chemistry

Herausgeber: Shaik, Sason; Stuyver, Thijs
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Electric-field-mediated chemistry is an emerging topic that is rapidly growing and fanning out in many directions. It involves theoretical and experimental aspects, as well as intense interplay between them, including breakthrough achievements such as the proof-of-principle that a Diels-Alder reaction, which involves two simultaneous C-C bond making events, can be catalysed or inhibited simply by changing the direction of an oriented external-electric field (OEEF). This productive interplay between the theoretical and experimental branches of chemistry is continuing, and gradually defining a n...