Discovery of Ba7Nb4MoO20-Based Materials and the Mechanism of Ultrafast Ion Conduction Via Dimers
Yuichi Sakuda
Gebundenes Buch

Discovery of Ba7Nb4MoO20-Based Materials and the Mechanism of Ultrafast Ion Conduction Via Dimers

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This book provides detailed descriptions of strategies for improving ion conductivity and the factors that result in high ion conductivity.In this book, discovery of novel materials that exhibit higher ion conductivity than practical materials is introduced to clarify the migration mechanism of oxide ions and protons.The book shows that the bulk conductivity of hexagonal perovskite-related oxide Ba7Nb3.8Mo1.2O20.1 in dry air is 1.1 mS/cm at 306 °C, which is 175 times higher than that of practical materials (ZrO2)0.92(Y2O3)0.08 (8YSZ). Also, as a new approach to the subject, by ab initio molec...