Keita Fuchise
Gebundenes Buch

Design and Precise Synthesis of Thermoresponsive Polyacrylamides

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In this thesis, the author describes versatile and easy-to-use methods to control the properties of thermoresponsive polyacrylamides by developing novel synthetic methods for end-functionalized poly( N -isopropylacrylamide) (PNIPAM) and block copolymers of poly( N,N -diethylacrylamide) (PDEAA). The synthesis of various urea end-functionalized PNIPAMs was achieved by the atom transfer radical polymerization (ATRP) and the click reaction. The phase transition temperature of PNIPAM in water was controlled depending on the strength of the hydrogen bonding of the urea groups introduced at the chain...