Copper and Iron Complexes in Organised Assemblies

Copper and Iron Complexes in Organised Assemblies

Structures, Spectral and Electrochemical Properties and Biomimetic Dioxygen Activating Reactions in Micellar Media

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Life processes proceed mainly within the complicated assemblies of molecules rather than in free solution. The reactions occurring in biological aggregates are equivalent to reactions inside micelles. Organic reactions in micelles are known to be interesting. This book describes our attempt to use micellar media for the first time to mimic the biological electron-transfer and dioxygen activation by metalloproteins. The electron-transfer properties and catecholase activities of copper(II) complexes and catechol dioxygenase activities of biomimetic iron(III) complexes have been successfully stud...