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Boronic Acids
Preparation and Applications in Organic Synthesis and Medicine
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For the first time, the whole field of organoboronic acids is presented in one comprehensive handbook.Professor Dennis Hall, a rising star within the community, covers all aspects of this important substance class, including applications in chemistry, biology and medicine. Staring with an introduction to the structure, properties, and preparation of boronic acid derivatives, together with an overview of their reactions and applications, the book goes on to look at metal-catalyzed borylation of alkanes and arenas, coupling reactions and rhodium-catalyzed additions of boronic acids to alkenes an...
For the first time, the whole field of organoboronic acids is presented in one comprehensive handbook.
Professor Dennis Hall, a rising star within the community, covers all aspects of this important substance class, including applications in chemistry, biology and medicine.
Staring with an introduction to the structure, properties, and preparation of boronic acid derivatives, together with an overview of their reactions and applications, the book goes on to look at metal-catalyzed borylation of alkanes and arenas, coupling reactions and rhodium-catalyzed additions of boronic acids to alkenes and carbonyl compounds. There follows chapters on copper-promoted C-O and C-N cross-coupling of boronic acids, recent applications in organic synthesis, as well as alpha-haloalkylboronic esters in asymmetric synthesis. Later sections deal with cycloadditions, organoboronic acids, oxazaborolidines as asymmetric inducers, and boronic acid based receptors and sensors. The whole is rounded off with experimental procedures, making this invaluable reading for organic, catalytic and medicinal chemists, as well as those working in organometallics.
AUS DEM INHALT:
Structure, properties, and preparation of boronic acid derivatives. Overview of their reactions and applications.
Metal-catalyzed borylation of alkanes and arenas via C-H activation for synthesis of boronic esters.
Coupling reactions of areneboronic acids or esters with aromatic electrophiles.
Rhodium-catalyzed additions of boronic acids to alkenes and carbonyl compounds.
Copper-promoted C-O and C-N cross-coupling of boronic acids.
Preparation of allylboronates and recent applications in organic synthesis.
Nulceophilic addition reactions of aryl and akenylboronic acids and their derivatives to imines and iminium ions.
Alpha-haloalkylboronic esters in asymmetric synthesis.
Cycloadditions and other additions to alkenyl- alkynyl-, and dienylboronic esters.
Organoboronic acids and organoborinic acids as Bronsted-Lewis acid catalysts in organic synthesis.
Oxazaborolidines as asymmetric inducers for the reduction of ketones and ketimines.
Boronic acid based receptors and sensors for saccharides.
Biological and medicinal applications of boronic acids.
Professor Dennis Hall, a rising star within the community, covers all aspects of this important substance class, including applications in chemistry, biology and medicine.
Staring with an introduction to the structure, properties, and preparation of boronic acid derivatives, together with an overview of their reactions and applications, the book goes on to look at metal-catalyzed borylation of alkanes and arenas, coupling reactions and rhodium-catalyzed additions of boronic acids to alkenes and carbonyl compounds. There follows chapters on copper-promoted C-O and C-N cross-coupling of boronic acids, recent applications in organic synthesis, as well as alpha-haloalkylboronic esters in asymmetric synthesis. Later sections deal with cycloadditions, organoboronic acids, oxazaborolidines as asymmetric inducers, and boronic acid based receptors and sensors. The whole is rounded off with experimental procedures, making this invaluable reading for organic, catalytic and medicinal chemists, as well as those working in organometallics.
AUS DEM INHALT:
Structure, properties, and preparation of boronic acid derivatives. Overview of their reactions and applications.
Metal-catalyzed borylation of alkanes and arenas via C-H activation for synthesis of boronic esters.
Coupling reactions of areneboronic acids or esters with aromatic electrophiles.
Rhodium-catalyzed additions of boronic acids to alkenes and carbonyl compounds.
Copper-promoted C-O and C-N cross-coupling of boronic acids.
Preparation of allylboronates and recent applications in organic synthesis.
Nulceophilic addition reactions of aryl and akenylboronic acids and their derivatives to imines and iminium ions.
Alpha-haloalkylboronic esters in asymmetric synthesis.
Cycloadditions and other additions to alkenyl- alkynyl-, and dienylboronic esters.
Organoboronic acids and organoborinic acids as Bronsted-Lewis acid catalysts in organic synthesis.
Oxazaborolidines as asymmetric inducers for the reduction of ketones and ketimines.
Boronic acid based receptors and sensors for saccharides.
Biological and medicinal applications of boronic acids.