Analyzing Transition Metal Carbonyl Clusters Using Skeletal Numbers
Enos Kiremire
Broschiertes Buch

Analyzing Transition Metal Carbonyl Clusters Using Skeletal Numbers

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The introductory section of the book provides examples of a selected method of how the skeletal numbers can be applied to analyze and categorize transition metal carbonyl clusters. It also puts a distinction between the skeletal number (K) of an element and the skeletal linkages (K) of two or more skeletal elements bound together in a cluster. The relationship between the empirical formula, K= ½ [E-V] and V=18n-2K for transition metal clusters or V= 8n-2K for main group elements is illustrated. The six fundamental equations for calculating cluster valence electrons (CVE) are provided. There a...