A Concise Semisynthesis of Hederagonic Acid
Christian Knittl-Frank
Broschiertes Buch

A Concise Semisynthesis of Hederagonic Acid

C-H Activation in Natural Product Synthesis

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Christian Knittl-Frank reports on the development of a novel synthetic route to the naturally occurring polyhydroxylated oleanane, hederagonic acid. Polyhydroxylated oleananes are a vast family of naturally occurring triterpenoids with versatile biological activities. A low commercial availability combined with high prices make these molecules interesting targets in natural product synthesis. The developed synthetic approach starts from oleanolic acid, a cheap material that is commercially available in bulk quantities. It features several multi-step one-pot reactions, allowing a minimization o...