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This book is divided into four main sections thoroughly analyzing the use of nanomaterials for water, air and soil solutions, and emphasizing environmental risks. Providing background on nanomaterials' two-decade study, it discusses the characterization and application of unconventional disinfectants, called antimicrobial nanomaterials, which fall into three categories and, while seemingly harmless, have potential hazards if applied improperly. Special attention is given to the process of remediation, synthetics techniques, and properties of nanomaterials, with examples to which new and…mehr
This book is divided into four main sections thoroughly analyzing the use of nanomaterials for water, air and soil solutions, and emphasizing environmental risks. Providing background on nanomaterials' two-decade study, it discusses the characterization and application of unconventional disinfectants, called antimicrobial nanomaterials, which fall into three categories and, while seemingly harmless, have potential hazards if applied improperly. Special attention is given to the process of remediation, synthetics techniques, and properties of nanomaterials, with examples to which new and trained readers in the field can relate and understand. * an interdisciplinary approach, aimed at scientists in physical chemistry, nanotechnology, and environmental sciences * includes applications of non-conventional techniques in environmental protection * furthers the development of applied nanoscience and nanotechnology * suggests new industrial projects and university courses addressing nanotechnology in and for the environment * includes applications for water, air and soil protection
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Boris I. Kharisov, PhD, is Professor and Researcher at the Universidad Autónoma de Nuevo León (UANL). He received his PhD in inorganic chemistry from the Moscow State University, Russia, in 1993. He holds two patents, has co-authored six books, five book chapters, 127 articles, and co-edited three invited special issues of international journals, and is the member of the editorial board of four journals. His specialties include coordination and inorganic chemistry, phthalocyanines, ultrasound, and nanotechnology. Oxana V. Kharissova, PhD, is Professor and Researcher at the UANL. She received her PhD in Materials from the Universidad Autónoma de Nuevo León, Mexico. She has co-authored three books, 60 articles, and has two patents. Her specialties include nanotechnology (carbon nanotubes, nanometals, fullerenes), and crystallography. H.V. Rasika Dias, PhD, is Professor of Chemistry at the University of Texas at Arlington. He received his PhD from University of California, Davis. Specializing in inorganic and organometallic chemistry, he has co-authored several patents and over 160 publications. His accolades include the 2009 Southwest Regional American Chemical Society Award.
Inhaltsangabe
Preface ix LIST OF CONTRIBUTORS xi LIST OF ABBREVIATIONS xv Part I Remediation with use of metals, metal oxides, complexes and composites 1 1 Groundwater Water Remediation by Static Diffusion Using Nano-Zero Valent Metals (Fe0, Cu0, Al0), n-FeHn+, n-Fe(OH)x, n-FeOOH, n-Fe-[OxHy](n+/.) 3 David D.J. Antia 2 Nanostructured Metal Oxides for Wastewater Disinfection 27 Erick R. Bandala, Marco Antonio Quiroz Alfaro, Mónica Cerro-López, and Miguel A. Méndez-Rojas 3 Cu2O-Based Nanocomposites for Environmental Protection: Relationship between Structure and Photocatalytic Activity, Application, and Mechanism 41 Liangbin Xiong, Huaqing Yu, Xin Ba, Wenpei Zhang, and Ying Yu 4 Multifunctional Nanocomposites for Environmental Remediation 71 Suying Wei, Jiahua Zhu, Hongbo Gu, Huige Wei, Xingru Yan, Yudong Huang, and Zhanhu Guo 5 Nanomaterials for the Removal of Volatile Organic Compounds from Aqueous Solutions 85 Amro El Badawy and Hafiz H.M. Salih 6 Hybrid Metal Nanoparticle-Containing Polymer Nanofibers for Environmental Applications 95 Yunpeng Huang, Shige Wang, Mingwu Shen, and Xiangyang Shi 7 Nanomaterials on the Basis of Chelating Agents, Metal Complexes, and Organometallics for Environmental Purposes 109 Boris I. Kharisov, Oxana V. Kharissova, and Ubaldo Ortiz Méndez Part II Remediation with use of carbon nanotubes 125 8 Carbon Nanotubes: Next-Generation Nanomaterials for Clean Water Technologies 127 Yit Thai Ong, Kian Fei Yee, Qian Wen Yeang, Sharif Hussein Sharif Zein, and Soon Huat Tan Part III Photo catalytical remediation 143 9 New Advances in Heterogeneous Photocatalysis for Treatment of Toxic Metals and Arsenic 145 Marta I. Litter and Natalia Quici 10 Nanostructured Titanium Dioxide for Photocatalytic Water Treatment 169 David G. Rickerby 11 Destruction of Chloroorganic Compounds with Nanophotocatalysts 183Rashid A. Khaydarov, Renat R. Khaydarov, and Olga Gapurova 12 Semiconductor Nanomaterials for Organic Dye Degradation and Hydrogen Production via Photocatalysis 193 Leticia M. Torres-Martínez, Isaías Juárez-Ramírez, and Mayra Z. Figueroa-Torres Part IV Nanoadsorbents and Nanofiltration 205 13 Advanced Oxidation Processes, Nanofiltration, and Application of Bubble Column Reactor 207 Sukanchan Palit 14 Carbon Nanomaterials as Adsorbents for Environmental Analysis 217 Chaudhery Mustansar Hussain 15 Application of Nanoadsorbents in Water Treatment 237 Amit Bhatnagar and Mika Sillanpää 16 Organo-Clay Nanohybrid Adsorbents in the Removal of Toxic Metal Ions 249 Peng Liu Part V Membranes on nanomaterials basis 269 17 Water Remediation Using Nanoparticle and Nanocomposite Membranes 271 Kian Fei Yee, Qian Wen Yeang, Yit Thai Ong, Vel Murugan Vadivelu, and Soon Huat Tan Part VI Green methods in nanomaterials synthesis 293 18 Green Methodologies in the Synthesis of Metal and Metal Oxide Nanoparticles 295 Aniruddha B. Patil and Bhalchandra M. Bhanage 19 An Environmentally Friendly and Green Approach for Synthesis and Applications of Silver Nanoparticles 313 Muniyandi Jeyaraj, Muralidharan Murugan, Kevin John Pulikotil Anthony, and Sangiliyandi Gurunathan 20 Green Synthesis of Nanomaterials Using Biological Routes 329 Rajesh Ramanathan, Ravi Shukla, Suresh K. Bhargava, and Vipul Bansal Part VII CO2 adsorption 349 21 Nanomaterials for Carbon Dioxide Adsorption 351 Luis Ángel Garza Rodríguez and Elsa Nadia Aguilera González Part VIII Intelligent nanomaterials 373 22 Development of Intelligent Nanomaterials as a Strategy to Solve Environmental Problems 375 Jose Ruben Morones-Ramírez Part IX Desalination 387 23 Engineered Nanomaterials for Purification and Desalination of Palatable Water 389 Vijay C. Verma, Swechha Anand, Mayank Gangwar, and Santosh K. Singh Part X Nanocatalysis 401 24 Nanocatalytic Wastewater Treatment System for the Removal of Toxic Organic Compounds 403 Sodeh Sadjadi 25 Catalyst Design Based on Nano-Sized Inorganic Core of Enzymes: Design of Environmentally Friendly Catalysts 429 Mohammad Mahdi Najafpour Part XI Nanosensors 443 26 Neutron-Fluence Nanosensors Based on Boron-Containing Materials 445 Levan Chkhartishvili Part XII Nanoreservoirs for hydrogen storage 451 27 Hydrogen Nanoreservoirs made of Boron Nitride 453 Levan Chkhartishvili Part XIII Fuel cells on nanomaterials basis 469 28 Fuel Cells with Nanomaterials for Ecologically Pure Transport 471 Gennady Gerasimov Part XIV Remediation of radionuclides 483 29 Humic Functional Derivatives and Nanocoatings for Remediation of Actinide-Contaminated Environments 485 Irina V. Perminova, Stepan N. Kalmykov, Natalia S. Shcherbina, Sergey A. Ponomarenko, Vladimir A. Kholodov, Alexander P. Novikov, Richard G. Haire, and Kirk Hatfield Part XV Environmental risks and toxicity 503 30 Environmental Risks of Nanotechnology: Evaluating the Ecotoxicity of Nanomaterials 505 Miguel A. Méndez-Rojas, José Luis Sánchez-Salas, Aracely Angulo-Molina, and Teresa de Jesús Palacios-Hernández 31 Environmental Risk, Human Health, and Toxic Effects of Nanoparticles 523 Jamuna Bai A. and Ravishankar Rai V. 32 Implications of the Use of Nanomaterials for Environmental Protection: Challenges in Designing Environmentally Relevant Toxicological Experiments 537 Rute F. Domingos and José P. Pinheiro Concluding Remarks 551 Author Index 555 Subject Index 559
Preface ix LIST OF CONTRIBUTORS xi LIST OF ABBREVIATIONS xv Part I Remediation with use of metals, metal oxides, complexes and composites 1 1 Groundwater Water Remediation by Static Diffusion Using Nano-Zero Valent Metals (Fe0, Cu0, Al0), n-FeHn+, n-Fe(OH)x, n-FeOOH, n-Fe-[OxHy](n+/.) 3 David D.J. Antia 2 Nanostructured Metal Oxides for Wastewater Disinfection 27 Erick R. Bandala, Marco Antonio Quiroz Alfaro, Mónica Cerro-López, and Miguel A. Méndez-Rojas 3 Cu2O-Based Nanocomposites for Environmental Protection: Relationship between Structure and Photocatalytic Activity, Application, and Mechanism 41 Liangbin Xiong, Huaqing Yu, Xin Ba, Wenpei Zhang, and Ying Yu 4 Multifunctional Nanocomposites for Environmental Remediation 71 Suying Wei, Jiahua Zhu, Hongbo Gu, Huige Wei, Xingru Yan, Yudong Huang, and Zhanhu Guo 5 Nanomaterials for the Removal of Volatile Organic Compounds from Aqueous Solutions 85 Amro El Badawy and Hafiz H.M. Salih 6 Hybrid Metal Nanoparticle-Containing Polymer Nanofibers for Environmental Applications 95 Yunpeng Huang, Shige Wang, Mingwu Shen, and Xiangyang Shi 7 Nanomaterials on the Basis of Chelating Agents, Metal Complexes, and Organometallics for Environmental Purposes 109 Boris I. Kharisov, Oxana V. Kharissova, and Ubaldo Ortiz Méndez Part II Remediation with use of carbon nanotubes 125 8 Carbon Nanotubes: Next-Generation Nanomaterials for Clean Water Technologies 127 Yit Thai Ong, Kian Fei Yee, Qian Wen Yeang, Sharif Hussein Sharif Zein, and Soon Huat Tan Part III Photo catalytical remediation 143 9 New Advances in Heterogeneous Photocatalysis for Treatment of Toxic Metals and Arsenic 145 Marta I. Litter and Natalia Quici 10 Nanostructured Titanium Dioxide for Photocatalytic Water Treatment 169 David G. Rickerby 11 Destruction of Chloroorganic Compounds with Nanophotocatalysts 183Rashid A. Khaydarov, Renat R. Khaydarov, and Olga Gapurova 12 Semiconductor Nanomaterials for Organic Dye Degradation and Hydrogen Production via Photocatalysis 193 Leticia M. Torres-Martínez, Isaías Juárez-Ramírez, and Mayra Z. Figueroa-Torres Part IV Nanoadsorbents and Nanofiltration 205 13 Advanced Oxidation Processes, Nanofiltration, and Application of Bubble Column Reactor 207 Sukanchan Palit 14 Carbon Nanomaterials as Adsorbents for Environmental Analysis 217 Chaudhery Mustansar Hussain 15 Application of Nanoadsorbents in Water Treatment 237 Amit Bhatnagar and Mika Sillanpää 16 Organo-Clay Nanohybrid Adsorbents in the Removal of Toxic Metal Ions 249 Peng Liu Part V Membranes on nanomaterials basis 269 17 Water Remediation Using Nanoparticle and Nanocomposite Membranes 271 Kian Fei Yee, Qian Wen Yeang, Yit Thai Ong, Vel Murugan Vadivelu, and Soon Huat Tan Part VI Green methods in nanomaterials synthesis 293 18 Green Methodologies in the Synthesis of Metal and Metal Oxide Nanoparticles 295 Aniruddha B. Patil and Bhalchandra M. Bhanage 19 An Environmentally Friendly and Green Approach for Synthesis and Applications of Silver Nanoparticles 313 Muniyandi Jeyaraj, Muralidharan Murugan, Kevin John Pulikotil Anthony, and Sangiliyandi Gurunathan 20 Green Synthesis of Nanomaterials Using Biological Routes 329 Rajesh Ramanathan, Ravi Shukla, Suresh K. Bhargava, and Vipul Bansal Part VII CO2 adsorption 349 21 Nanomaterials for Carbon Dioxide Adsorption 351 Luis Ángel Garza Rodríguez and Elsa Nadia Aguilera González Part VIII Intelligent nanomaterials 373 22 Development of Intelligent Nanomaterials as a Strategy to Solve Environmental Problems 375 Jose Ruben Morones-Ramírez Part IX Desalination 387 23 Engineered Nanomaterials for Purification and Desalination of Palatable Water 389 Vijay C. Verma, Swechha Anand, Mayank Gangwar, and Santosh K. Singh Part X Nanocatalysis 401 24 Nanocatalytic Wastewater Treatment System for the Removal of Toxic Organic Compounds 403 Sodeh Sadjadi 25 Catalyst Design Based on Nano-Sized Inorganic Core of Enzymes: Design of Environmentally Friendly Catalysts 429 Mohammad Mahdi Najafpour Part XI Nanosensors 443 26 Neutron-Fluence Nanosensors Based on Boron-Containing Materials 445 Levan Chkhartishvili Part XII Nanoreservoirs for hydrogen storage 451 27 Hydrogen Nanoreservoirs made of Boron Nitride 453 Levan Chkhartishvili Part XIII Fuel cells on nanomaterials basis 469 28 Fuel Cells with Nanomaterials for Ecologically Pure Transport 471 Gennady Gerasimov Part XIV Remediation of radionuclides 483 29 Humic Functional Derivatives and Nanocoatings for Remediation of Actinide-Contaminated Environments 485 Irina V. Perminova, Stepan N. Kalmykov, Natalia S. Shcherbina, Sergey A. Ponomarenko, Vladimir A. Kholodov, Alexander P. Novikov, Richard G. Haire, and Kirk Hatfield Part XV Environmental risks and toxicity 503 30 Environmental Risks of Nanotechnology: Evaluating the Ecotoxicity of Nanomaterials 505 Miguel A. Méndez-Rojas, José Luis Sánchez-Salas, Aracely Angulo-Molina, and Teresa de Jesús Palacios-Hernández 31 Environmental Risk, Human Health, and Toxic Effects of Nanoparticles 523 Jamuna Bai A. and Ravishankar Rai V. 32 Implications of the Use of Nanomaterials for Environmental Protection: Challenges in Designing Environmentally Relevant Toxicological Experiments 537 Rute F. Domingos and José P. Pinheiro Concluding Remarks 551 Author Index 555 Subject Index 559
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