Chao-Jun Li, Tak-Hang Chan

Comprehensive Organic Reactions in Aqueous Media

• Gebundenes Buch

Produktbeschreibung

Organic reactions in water have proven a useful synthetic tool, and provide cost-efficient, safe, and environmentally friendly alternatives to organic-solvent based reactions. This field has been greatly expanded over the last decade, and currently there are many diverse applications in both industry and academic laboratories. Authored by world-renowned experts and extensively updated, this book provides the most comprehensive coverage of aqueous organic reactions available.

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Organische Reaktionen in wässriger Lösung - dieses neue Themengebiet wird dem Leser hier umfassend vorgestellt. Zunächst werden theoretische Grundlagen wie die Eigenschaften von Wasser diskutiert; es folgen sechs Kapitel zu wichtigen Reaktionsgruppen (unter anderem pericyclische, nucleophile, metallvermittelte und metallkatalysierte Reaktionen) und schließlich Informationen zur industriellen Anwendung.

Produktdetails

• Wiley-Interscience
• Verlag: Wiley & Sons
• 2. Aufl.
• Seitenzahl: 448
• Erscheinungstermin: 1. Mai 2007
• Englisch
• Abmessung: 235mm x 157mm x 28mm
• Gewicht: 730g
• ISBN-13: 9780471761297
• ISBN-10: 047176129X
• Artikelnr.: 22579693

Autorenporträt

Chao-Jun Li, PhD, is Professor at McGill University in Canada. Professor Li began teaching at Tulane University in 1994 and received an NSF CAREER Award for work done from 1998-2002, the Outstanding Young Oversea Scientist Award from the NSFC in 2001, and the U.S. Presidential Green Chemistry Challenge Award in Academia for 2001. Dr. Li moved to McGill University in 2003 and received a Canada Research Chair in Green Chemistry (Tier I). He coauthored the popular first edition of Organic Reactions in Aqueous Media (Wiley). Tak-Hang Chan, PhD, is Professor Emeritus at McGill University in Canada and Chair Professor of Organic Chemistry at the Hong Kong Polytechnic University in Hong Kong. In 1993, Professor Chan received the prestigious R.U. Lemieux Award of the Canadian Society of Chemistry. A pioneer in green chemistry, he is a Fellow of the Royal Society of Canada and holds Honorary Professorships at Academia Sinica, Peking University, and Lanzhou University. He was coauthor of the first edition.

Inhaltsangabe

PREFACE TO THE SECOND EDITION. 1. INTRODUCTION. 1.1 The Structure and Forms
of Water. 1.2 Properties of Water. 1.3 Solvation. 1.4 Hydrophobic Effect.
1.5 Salt Effect. 1.6 Water Under Extreme Conditions. References. 2.
ALKANES. 2.1 Oxygenation of Alkanes. 2.2 Halogenation of Alkanes. 2.3
Formation of Carbon-Carbon Bonds. 2.4 D/H Exchange of Alkanes in Water.
References. 3. ALKENES. 3.1 Reduction. 3.2 Electrophilic Additions. 3.3
Radical Reactions of Alkenes. 3.4 Carbene Reactions. 3.5 Alkene
Isomerization. 3.6 Transition-Metal Catalyzed C-C Formation Reactions. 3.7
Olefin Metathesis. 3.8 Reaction of Allylic C-H Bond. 4. ALKYNES. 4.1
Reaction of Terminal Alkynes. 4.2 Additions of C=C bonds. 4.3
Transition-Metal Catalyzed Cycloadditions. 4.4 Other Reactions. References.
5. ALCOHOLS, PHENOLS, ETHERS, THIOLS, AND THIOETHERS. 5.1 Oxidation of
Alcohols. 5.2 Substitutions/Elimination. 5.3 Addition of Alcohols, Phenols,
and Thiols to Alkene and Alkyne Bonds. 5.4 Addition of Alcohols to C=O
Bonds: Esterification and Acetal Formations. 5.5 Reaction of Ethers and
Cyclic Ethers. 5.6 Reaction of Sulfur Compounds. 6. ORGANIC HALIDES. 6.1
General. 6.2 Reduction. 6.3 Elimination Reactions. 6.4 Nucleophilic
Substitutions. 6.5 Reductive Coupling. 6.6 Carbonylation of Organic
Halides. 6.7 Transition-Metal Catalyzed Coupling Reactions. References. 7.
AROMATIC COMPOUNDS. 7.1 General. 7.2 Substitution Reactions. 7.3 Oxidation
Reactions. 7.4 Reductions. References. 8. ALDEHDYE AND KETONES. 8.1
Reduction. 8.2 Oxidation. 8.3 Nucleophilic Addition: C-C Bond Formation.
8.4 Pinacol Coupling. 8.5 Other Reactions (Halogenation and Oxidation of
a-H). References. 9. CARBOXYLIC ACIDS AND DERIVATIVES. 9.1 General. 9.2
Carboxylic Acids. 9.3 Carboxylic Acid Derivatives. References. 10.
CONJUGATED CARBONYL COMPOUNDS. 10.1 Reduction. 10.2 Epoxidation,
Dihydroxylation, Hydroxyamination. 10.3 Conjugate Addition: Heteroatom.
10.4 C-C Bond Formation. 10.5 Other Reactions. References. 11. NITROGEN
COMPOUNDS. 11.1 Amines. 11.2 Imines. 11.3 Diazo Compounds. 11.4 Azides.
11.5 Nitro Compounds. References. 12. PERICYCLIC REACTIONS. 12.1
Introduction. 12.2 Diels-Alder Reactions. 12.3 Sigmatropic Rearrangements.
12.4 Photochemical Cycloaddition Reactions. References. INDEX.

Rezensionen

"Diese Aktualisierung einer klassischen Monographie fasst die bedeutenden Fortschritte auf dem Gebiet organischer Reaktionen in wässriger Phase in den letzten Jahren hervorragend zusammen."
Angewandte Chemie
2008-120/11