Andrzej Wieckowski, Carol Korzeniewski, Björn Braunschweig

Vibrational Spectroscopy at Electrified Interfaces

• Gebundenes Buch

Produktbeschreibung

Edited by highly cited researchers, Vibrational Spectroscopy of Electrified Interfaces highlights modern vibrational techniques ranging from Raman, infrared and non-linear optical spectroscopy to inelastic electron scattering and their application to study electrified interfaces. Providing molecular-level information on the structure and composition of surfaces and interfaces, this first book available on the topic addresses theory, techniques, and applications across a wide range of interfaces in the physical and biological sciences, including those in biological, geochemical, and power devices such as batteries, solar and fuel cells.

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Reviews the latest theory, techniques, and applications Surface vibrational spectroscopy techniques probe the structure and composition of interfaces at the molecular level. Their versatility, coupled with their non-destructive nature, enables in-situ measurements of operating devices and the monitoring of interface-controlled processes under reactive conditions. Vibrational Spectroscopy at Electrified Interfaces explores new and emerging applications of Raman, infrared, and non-linear optical spectroscopy for the study of charged interfaces. The book draws from hundreds of findings reported in the literature over the past decade. It features an internationally respected team of authors and editors, all experts in the field of vibrational spectroscopy at surfaces and interfaces. Content is divided into three parts: * Part One, Nonlinear Vibrational Spectroscopy, explores properties of interfacial water, ions, and biomolecules at charged dielectric, metal oxide, and electronically conductive metal catalyst surfaces. In addition to offering plenty of practical examples, the chapters present the latest measurement and instrumental techniques. * Part Two, Raman Spectroscopy, sets forth highly sensitive approaches for the detection of biomolecules at solid-liquid interfaces as well as the use of photon depolarization strategies to elucidate molecular orientation at surfaces. * Part Three, IRRAS Spectroscopy (including PM-IRRAS), reports on wide-ranging systems-from small fuel molecules at well-defined surfaces to macromolecular complexes-that serve as the building blocks for functional interfaces in devices designed for chemical sensing and electric power generation. The Wiley Series on Electrocatalysis and Electrochemistry is dedicated to reviewing important advances in the field, exploring how these advances affect industry. The series defines what we currently know and can do with our knowledge of electrocatalysis and electrochemistry as well as forecasts where we can expect the field to be in the future.

Produktdetails

• Verlag: John Wiley & Sons / Wiley
• Seitenzahl: 440
• Erscheinungstermin: 10. September 2013
• Englisch
• Abmessung: 240mm x 161mm x 28mm
• Gewicht: 824g
• ISBN-13: 9781118157176
• ISBN-10: 1118157176
• Artikelnr.: 37315961

Autorenporträt

ANDRZEJ WIECKOWSKI, PhD, is Emeritus Professor of Chemistry at the University of Illinois and the North American Editor for Electrochimica Acta. His research focused on electrode surface structure in relation to electrocatalysis, molecular-level studies of surface oxidation and reduction processes, and surface motional behavior in electrocatalysis. CAROL KORZENIEWSKI, PhD, is Professor of Chemistry at Texas Tech University. Her research, supported by the U. S. National Science Foundation, Department of Energy, and Department of Defense, centers on the use of vibrational spectroscopy to probe interfacial processes in electrochemistry. BJÖRN BRAUNSCHWEIG, PhD, is a Postdoctoral Research Associate at the University of Erlangen-Nuremberg and was a recipient of the Feodor Lynen Research Fellowship of the Alexander von Humboldt Foundation. His junior research group focuses on the nonlinear optical spectroscopy of charged interfaces.

Inhaltsangabe

Preface to the Wiley Series on Electrocatalysis and Electrochemistry vii
Foreword ix by Masatoshi Osawa Preface xi Contributors xiii Part One
Nonlinear Vibrational Spectroscopy 1. Water Hydrogen Bonding Dynamics at
Charged Interfaces Observed with Ultrafast Nonlinear Vibrational
Spectroscopy 3 Emily E. Fenn and Michael D. Fayer 2. SFG Studies of
Oxide-Water Interfaces: Protonation States, Water Polar Orientations, and
Comparison with Structure Results from X-Ray Scattering 48 Y. Ron Shen and
Glenn A. Waychunas 3. Vibrational Sum Frequency Generation Spectroscopy of
Interfacial Dynamics 85 Christopher M. Berg and Dana D. Dlott 4.
Spectroscopy of Electrifi ed Interfaces with Broadband Sum Frequency
Generation: From Electrocatalysis to Protein Foams 120 Björn Braunschweig,
Prabuddha Mukherjee, Robert B. Kutz, Armin Rumpel, Kathrin Engelhardt,
Wolfgang Peukert, Dana D. Dlott, and Andrzej Wieckowski Part Two Raman
Spectroscopy 5. Surface-Enhanced Resonance Raman Scattering (SERRS) Studies
of Electron-Transfer Redox-Active Protein Attached to Thiol-Modified Metal:
Case of Cytochrome c 153 Agata Królikowska 6. Depolarization of
Surface-Enhanced Raman Scattering Photons from a Small Number of Molecules
on Metal Surfaces 220 Fumika Nagasawa, Mai Takase, Hideki Nabika, and Kei
Murakoshi Part Three IRRAS Spectroscopy (Including PM-IRRAS) 7. DFT and In
Situ Infrared Studies on Adsorption and Oxidation of Glycine, l-Alanine,
and l-Serine on Gold Electrodes 241 Andrea P. Sandoval, José Manuel Orts,
Antonio Rodes, and Juan M. Feliu 8. Composition, Structure, and Reaction
Dynamics at Electrode-Electrolyte Interfaces Using Infrared Spectroscopy
266 Angel Cuesta 9. Vibrational Stark Effect at Halide Precovered Cu(100)
Electrodes 307 Melanie Röefzaad, Duc Thanh Pham, and Klaus Wandelt 10.
Vibrational Spectroscopy of the Ionomer-Catalyst Interface 327 Ian
Kendrick, Jonathan Doan, and Eugene S. Smotkin 11. In Situ PM-IRRAS Studies
of Biomimetic Membranes Supported at Gold Electrode Surfaces 345 Annia H.
Kycia, ZhangFei Su, Christa L. Brosseau, and Jacek Lipkowski Index 418