William Henderson, Scott McIndoe

Mass Spectrometry of Inorganic and Organometallic Compounds

Tools - Techniques - Tips

• Broschiertes Buch

Produktbeschreibung

Mass Spectrometry of Inorganic and Organometallic Compounds is the first modern book to treat inorganic and organometallic mass spectrometry simultaneously. It is textbook and handbook in one: As a textbook, it introduces the techniques and gives hints on how to apply the various techniques; as a handbook, it lists all available ionization techniques for just about any given compound. Mass Spectrometry of Inorganic and Organometallic Compounds will instill the synthetic inorganic and organometallic chemist with the confidence to apply some of the new techniques to their characterization problems.

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This is the first modern book to treat inorganic and organometallic mass spectrometry simultaneously. It is textbook and handbook in one; as a textbook it introduces the techniques and gives hints on how to apply the various techniques, as a handbook it lists all available ionization techniques for just about any given compound. The book also includes non-mathematical explanations of how modern MS instruments work

Mass Spectrometry of Inorganic and Organometallic Compounds will inspire the synthetic inorganic and organometallic chemist with the confidence to apply some of the new techniques to their characterization problems.

Produktdetails

• Verlag: Wiley & Sons
• 1. Auflage
• Seitenzahl: 304
• Erscheinungstermin: 1. April 2005
• Englisch
• Abmessung: 246mm x 189mm x 18mm
• Gewicht: 645g
• ISBN-13: 9780470850169
• ISBN-10: 0470850167
• Artikelnr.: 14069058

Autorenporträt

William Henderson is the author of Mass Spectrometry of Inorganic and Organometallic Compounds: Tools - Techniques - Tips, published by Wiley. J. Scott McIndoe is the author of Mass Spectrometry of Inorganic and Organometallic Compounds: Tools - Techniques - Tips, published by Wiley.

Inhaltsangabe

Preface. List of commonly-used abbreviations. Chapter 1 Fundamentals. _1.1
Introduction. _1.2 Inlets. _1.3 Collision-induced dissociation. _1.4
Detectors. _1.5 Mass resolution. _1.6 Data processing. _1.7 Isotopes.
_References. Chapter 2 Mass analysers. 2.1 Introduction. 2.2 Sectors. 2.3
Quadrupoles. 2.4 Quadrupole Ion Trap. ¯2.5 Time-of-flight. ¯2.6 Fourier
Transform Ion Cyclotron Resonance. ¯References. Chapter 3 Ionisation
techniques. 3.1 Introduction. 3.2 Electron ionisation. 3.3 Chemical
Ionisation. 3.4 Field ionisation / Field desorption. 3.5 Plasma Desorption.
3.6 Fast Atom Bombardment / Liquid Secondary Ion Mass Spectrometry. 3.7
Matrix Assisted Laser Desorption Ionisation. 3.8 Inductively Coupled Plasma
Mass Spectrometry. 3.9 Electrospray ionisation. References. Chapter 4 The
ESI MS behaviour of simple inorganic compounds. 4.1 Introduction. 4.2
Simple metal salts. 4.3 Polyanions formed by main group elements. 4.4
Oxoanions formed by main group elements. 4.5 Borane anions. 4.6 Fullerenes.
4.7 Inorganic phosphorus compounds: phosphoranes and cyclophosphazenes. 4.8
Summary. References. Chapter 5 The ESI MS behaviour of coordination
complexes. 5.1 Introduction. 5.2 Charged, "simple" coordination complexes.
5.3 (Neutral) metal halide coordination complexes. 5.4 Metal complexes of
polydentate oxygen donor ligands: polyethers, crown ethers, cryptands and
calixarenes. 5.5 Porphyrins and metalloporphyrins. 5.6 Metal alkoxides -
highly moisture-sensitive coordination compounds. 5.7 b-Diketonate
complexes. 5.8 Metal complexes of carbohydrates. 5.9 Metal complexes of
amino acids, peptides and proteins. 5.10 Oxoanions, polyoxoanions and
related species. 5.11 Metal clusters. 5.12 Compounds with anionic sulfur
and selenium donor ligands. 5.13 Characterisation of metal-based anticancer
drugs, their reaction products and metabolites. 5.14 In situ formation of
coordination complexes as an ionisation technique. 5.15 Summary.
References. Chapter 6 The ESI MS behaviour of main group organometallic
compounds. 6.1 Introduction. 6.2 Organometallic derivatives of group 14
elements. 6.3 Organometallic derivatives of group 15 elements. 6.4
Organometallic derivatives of group 16 elements; organo-sulfur, -selenium
and -tellurium compounds. 6.5 Organomercury compounds. 6.6 Other
organometallic derivatives. 6.7 Summary. References. Chapter 7 The ESI MS
behaviour of transition metal and lanthanide organometallic compounds. 7.1
Introduction. 7.2 Metal carbonyl complexes. 7.3 Metal isocyanide complexes.
7.4 Metal cyclopentadienyl and related complexes. 7.5 Metal h3-allyl
complexes. 7.6 Metal arene complexes. 7.7 Formation of p-hydrocarbon
complexes and their use as an ionisation aid. 7.8 Metal-acetylene/acetylide
complexes, and complexes of metal-acetylides. 7.9 Transition metal s-alkyl
and aryl complexes. 7.10 Mass spectrometry of lanthanide organometallic
complexes. 7.11 Summary. References. Chapter 8 A selection of special
topics. 8.1 Introduction. 8.2 The characterisation of dendrimers using ESI
and MALDI-TOF MS techniques. 8.3 Investigating the formation of
supramolecular coordination assemblies using ESI MS. 8.4 Using ESI MS as a
tool for directing chemical synthesis: A case studyinvolving the platinum
metalloligands [Pt2(m-E)2(PPh3)4] (E = S, Se). 8.5 Applications of ESI MS
in the detection of reactive intermediates and catalyst screening.
References. Appendix 1 Naturally occurring isotopes. Appendix 2 Periodic
table of the elements. Appendix 3 Alphabetical list of elements. Appendix 4
Mass Spectrometry Glossary of Terms. Appendix 5 Useful sources of
information on mass spectrometry.

Rezensionen

Valuable addition to those already written covering mass spectrometry. ( Reviews , June 2008)