B. K. Hodnett

Heterogeneous Catalytic Oxidation

Fundamental and Technological Aspects of the Selective and Total Oxidation of Organic Compounds

• Gebundenes Buch

Produktbeschreibung

Im Mittelpunkt dieses Bandes stehen sieben Fallstudien aus dem Gebiet der heterogen-katalytischen Oxidation; ihnen vorangestellt sind allgemeinere Informationen zur Katalyse und zur Oxidation. Jede Fallstudie widmet sich den Grundlagen und der Technologie einer bestimmten Reaktionsklasse, wobei 5 bis 6 Prinzipien herausgearbeitet werden, die allen heterogen-katalytischen Oxidationen gemeinsam sind. Der Stoff ist sehr anschaulich aufgearbeitet, mit vielen Diagrammen und Abbildungen. (04/00)

Produktdetails

• Verlag: Wiley & Sons
• 1. Auflage
• Seitenzahl: 360
• Erscheinungstermin: 13. Juli 2000
• Englisch
• Abmessung: 240mm x 161mm x 24mm
• Gewicht: 624g
• ISBN-13: 9780471489948
• ISBN-10: 0471489948
• Artikelnr.: 09430184

Autorenporträt

B. K. Hodnett is the author of Heterogeneous Catalytic Oxidation: Fundamental and Technological Aspects of the Selective and Total Oxidation of Organic Compounds, published by Wiley.

Inhaltsangabe

Preface 1 General Introduction 1.1 Presentation of Material 1.2 The Role
and Importance of Heterogeneous Catalytic Oxidation Processes in the
Chemical Industry References to Chapter 1 2 Introduction to Heterogeneous
Catalysis 2.1 Macroscopic and Microscopic Structure of Heterogeneous
Catalysts 2.2 The Five Basic Steps in Heterogeneous Catalysis 2.3 Testing
of Heterogeneous Catalysts 2.4 Diffusion 2.5 Adsorption at the Gas-Solid
Interface 2.6 Kinetics of Oxidation Reactions 2.7 Characterization of
Oxidation Catalysts References to Chapter 2 3 General Principles of
Heterogeneous Catalytic Oxidation 3.1 Generic Features of Catalytic
Oxidation Reactions 3.2 The Mode of Activation of the Hydrocarbon and
Discriminating Capacity of Active Sites in Oxidation Catalysis 3.3 Types of
Active Oxygen Species Involved in Oxidation Catalysis 3.4 Structural
Features of Oxidation Catalysts References to Chapter 3 4 Propene Oxidation
to Acrolein: Allylic Oxidation over Catalysts with Highly Mobile Oxygen
Anions 4.1 Introduction 4.2 The Composition of Multicomponent Bismuth
Molybdate Catalysts for Propene Oxidation 4.3 The Surface Allyl Species 4.4
Source of Oxygen Inserted into Propene to Form Acrolein 4.5 Oxygen
Transport within Bismuth Molybdate Catalysts 4.6 The Overall Reaction
Mechanism References to Chapter 4 5 Oxidation Activation of Alkanes:
Oxidation of n-butane to Maleic Arthydride 5.1 Introduction 5.2
Technologies for the Production of Maleic Anhydride 5.3 The Preparation,
Structure and Performance of Vanadium Phosphorus Oxide Catalysts 5.4
Activation of n-butane 5.5 The Nature of the Active Site and the Reaction
Mechanism 5.6 Conclusions References to Chapter 5 6 Epoxidation of Alkenes:
Reactivity of Electrophilie Oxygen Species 6.1 Introduction 6.2 Technology
for Ethylene Oxide Production 6.3 Catalyst Composition, Structure and
Performance 6.4 Reaction Kinetics and Network 6.5 The Nature of the Oxygen
Species on and under the Silver Surface 6.6 Reactivity of Oxygen Species on
Silver References to Chapter 6 7 Catalytic Combustion 7.1 Introduction 7.2
Environmental Applications of Catalytic Combustion 7.3 Principles of
Catalytic Combustion 7.4 Choice of Materials for the Construction of
Combustion Catalysts 7.5 Poisoning of Combustion Catalysts 7.6 Reactivity
of the Substrate 7.7 Kinetics of Catalytic Combustion Reactions 7.8 Nature
of the Active Species of Working Precious Metal Catalysts References to
Chapter 7 8 Activation and Insertion of Nitrogen into Organic Compounds 8.1
Introduction 8.2 Technology for Propene Ammoxidation 8.3 Catalysts Used in
Ammoxidation 8.4 The Ammoxidation Reaction Network 8.5 Mechanism of
Nitrogen Insertion in Ammoxidation 8.6 Nitrogen Insertion in Ammoxidation
References to Chapter 8 9 Catalytic Oxidation Reactions Involving Chlorine:
Oxychlorination and the Oxidative Destruction of Chlorinated Hydrocarbons
9.1 Introduction 9.2 Vinyl Chloride by Oxychlorination 9.3 Technology for
Vinyl Chloride Production 9.4 Oxychlorination Catalyst Composition,
Preparation and Characterization 9.5 The Mechanism of Oxychlorination 9.6
Destruction of Chlorinated Hydrocarbons by Catalytic Oxidation 9.7
By-product Formation during the Catalytic Oxidation of Chlorinated
Hydrocarbons 9.8 Polychlorinated Biphenyls, Dioxins and the Environment
References to Chapter 9 10 Oxidation Reactions Catalysed by Zeolites and
Structured Mesoporous Materials 10.1 Zeolites 10.2 Redox Molecular Sieves
10.3 Structured Mesoporous Silicates in Oxidation Reactions References to
Chapter 10 Index

Rezensionen

"...a clearly written, nicely illustrated, well-referenced book." (Chemistry in Britain, September 2000)
"Highly recommended..." (Focus on Catalyst, February 2001)
"...the author has accomplished an aggressive goal...The book is well written and will be appreciated by both the newcomer and expert in the field." (Cattech Vol. 6, No. 2, 2002)