Al Sattelberger / Inc. Inorganic Syntheses / Bodie E. Douglas

Inorganic Syntheses, Volume 35

Herausgegeben von Rauchfuss, Thomas

• Gebundenes Buch

Produktbeschreibung

The Inorganic Syntheses series provides all users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely compounds.

Includes complete, up-to-date procedures involving important inorganic substances
Contains subject, contributor, and formula indexes

Produktdetails

• Inorganic Syntheses Vol.35
• Verlag: Wiley & Sons
• 1. Auflage
• Seitenzahl: 224
• Erscheinungstermin: 27. September 2010
• Englisch
• Abmessung: 231mm x 152mm x 15mm
• Gewicht: 440g
• ISBN-13: 9780471682554
• ISBN-10: 0471682551
• Artikelnr.: 20802563

Autorenporträt

Thomas Rauchfuss received his undergraduate degree from the University of Puget Sound (1971) and his Ph.D. from Washington State University (1976). He has studied overseas at the following institutions: the Australian National University, University of Auckland, University of Strasbourg, and the Technical University of Karlsruhe. He is interested in all aspects of the synthesis and reactivity of inorganic, organometallic, and main-group compounds and materials.?He is a winner of the prestigious ACS Award in Inorganic Chemistry, and is Fellow of both the American Chemical Society and the Japan Society for the Promotion of Science.?Among others, Dr. Rauchfuss has held the Guggenheim Fellowship as well as the Alfred P. Sloan Fellowship, and has written numerous papers and book chapters.

Inhaltsangabe

Preface. Contributors. Dedication. Notice to Contributors and Checkers. Toxic Substances and Laboratory Hazards. Chapter One COMPLEXES OF BULKY ß
DIKETIMINATE LIGANDS. 1. Introduction. 2. ß
Diketiminate Precursors HL¯Me,Me3 and TlL¯Me,Me3 (L¯Me,Me3 = 2,4
Bis
(Mesitylimido)Pentyl). 3. ß
Diketiminate Precursors L¯Me,iPr2H, [¯LMe,iPr2Li]x, and [L¯tBu,iPr2K]x (L¯Me,iPr2 = 2,4
Bis
(2,6
Diisopropylphenylimido)Pentyl; L¯tBu,iPr2 = 2,2,6,6
Tetramethyl
3,5
Bis
(2,6
Diisopropylphenylimido)Heptyl). 4. ß
Diketiminate Precursors L¯tBu,iPr2H and L¯tBu,iPr2Li(THF) (L¯tBu,iPr2=2,2,6,6
Tetramethyl
3,5
Bis
(2,6
Diisopropylphenylimido)Heptyl). 5. Scandium Trichloride Tris(Tetrahydrofuran) and ß
Diketiminate
Supported Scandium Chloride Complexes. 6. ß
Diketiminate
Supported Titanium and Vanadium Dichloride Complexes. 7. ß
Diketiminate
Supported Vanadium and Chromium Chloride Complexes. 8. ß
Diketiminate
Supported Manganese and Zinc Complexes. 9. Iron 2,4
Bis
(2,6
Diisopropylphenylimido)Pentyl Chloride (L¯Me,iPr2FeCl). 10. Iron 2,2,6,6
Tetramethyl
3,5
Bis
(2,6
Diisopropylphenylimido)Heptyl Chloride (L¯tBu,iPr2FeCl). 11. Cobalt 2,2,6,6
Tetramethyl
3,5
Bis
(2,6
Diisopropylphenylimido) Heptyl Chloride (L¯tBu,iPr2CoCl). 12. ß
Diketiminate
Supported Nickel(II) and Nickel(I) Complexes of L¯Me,Me3 (L¯Me,Me3 = 2,4
Bis
(Mesitylimido)Pentyl). 13. Nickel 2,4
Bis
(2,6
Diisopropylphenylimido)Pentyl Chloride Dimer, [L¯Me,iPr2Ni(µ
Cl)]2. 14. Bis[Copper 2,4
Bis
(2,4,6
Trimethylphenylimido)Pentyl] Toluene, (L¯Me,Me3Cu)2(µ
n²:n²
C7H8). 15. Copper 2,4
Bis
(2,6
Diisopropylphenylimido)Pentyl Chloride (L¯Me,iPr2CuCl). Chapter Two BORON CLUSTER COMPOUNDS. 16. Salts of Dodecamethylcarba
closo
Dodecaborate(
) Anion, CB11Me12, and the Radical Dodecamethylcarba
closo
Dodecaboranyl, CB11Me12. 17. Cesium Dodecahydroxy
closo
Dodecaborate, Cs2[B12(OH)12]. Chapter Three COORDINATION COMPOUNDS. 18. Pentaaquanitrosylchromium Sulfate. 19. The Tetradentate Bispidine Ligand Dimethyl
(3,7
Dimethyl
9
oxo
2,4
bis(2
pyridyl)
3,7
Diazabicyclo[3.3.1]nonane)
1, 5
dicarboxylate and Its Copper(ll) Complex. 20. Tris(2
Picolinyl)Methane and Its Copper(I) Complex. Chapter Four CARBENE LIGANDS AND COMPLEXES. 21. 1,3
Dialkyl
Imidazole
2
Ylidenes. 22. A Chelating Rhodium N
Heterocyclic Carbene Complex by Transmetallation from a Silver
NHC Intermediate. 23. Rhodium and Iridium N
Heterocyclic Carbene Complexes from Imidazolium Carboxylates. Chapter Five FUNCTIONAL LIGANDS AND COMPLEXES. 24. N
tert
Butyl ortho
Aminophenol, ortho
Iminoquinone, and a Zirconium(IV) bis(Aminophenolate) Complex. 25. Synthesis of the Water
Soluble Bidentate (P, N) Ligand PTN(Me) (PTN(Me) = 7
Phospha
3
methyl
1,3,5
triazabicyclo[3.3.1]nonane). 26. Synthesis of Metal
Organic Frameworks: MOF
5 and MOF
177. Chapter Six ORGANOMETALLIC REAGENTS. 27. Tricarbonyl 1,3,5
Trimethyl
1,3,5
Triazacyclohexane Complexes of Chromium(0), Molybdenum(0), and Tungsten(0) [M(CO)3(Me3TACH) (M = Cr, Mo, W)]. 28. Manganese Tricarbonyl Transfer (MTT) Agents. 29. Bis(1,5
Cyclooctadiene)Nickel(0). 30. Sodium (n¯5
Cyclopentadienyl)Tris(Dimethylphosphito
P) Cobaltate(III), Na[(C5H5)Co{P(O)(OMe)2}3]. Chapter Seven BIO
INSPIRED IRON AND NICKEL COMPLEXES. 31. Iron
Cyanocarbonyl Complexes [PPN][Fe(CO)4(CN)] and [PPN][FeBr(CO)3(CN)2]. 32. Nickel Complexes of Bis(Diethylphosphinomethyl) Methylamine. 33. Monomeric Iron(II) Complexes Having Two Sterically Hindered Arylthiolates. 34 (1,3
Propanedithiolato)
Hexacarbonyldiiron and Cyanide Derivatives. Chapter Eight RUTHENIUM COMPLEXES. 35. Ruthenium(II)
Chlorido Complexes of Dimethylsulfoxide. 36. Synthesis of Chloride
Free Ruthenium(II) Hexaaqua Tosylate, [Ru(H2O)6]tos2. 37. Basic Ruthenium Acetate and Mixed Valence Derivatives. 38. Di
µ
Chloro(Ethylbenzoate)Diruthenium(II), [(n¯6
etb)RuCl2]2. Chapter Nine IRIDIUM COMPLEXES. 39. The Diphosphine tfepma and its Diiridium Complex Ir2¯0,II(tfepma)3Cl2. 40. Heteroleptic Cyclometalated Iridium(III) Complexes. 41. Oxygen and Carbon Bound Acetylacetonato Iridium(III) Complexes. Contributor Index. Subject Index. Formula Index.