Produktbild: Next-Generation Electrochromic Devices
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Next-Generation Electrochromic Devices From Multifunctional Materials to Smart Glasses

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Beschreibung

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

23.07.2025

Abbildungen

150 schwarz-weiße und 50 farbige Abbildungen

Verlag

Wiley-VCH

Seitenzahl

368

Maße (L/B/H)

25,2/17,9/2,7 cm

Gewicht

666 g

Auflage

1. Auflage

Sprache

Englisch

ISBN

978-3-527-34925-8

Beschreibung

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

23.07.2025

Abbildungen

150 schwarz-weiße und 50 farbige Abbildungen

Verlag

Wiley-VCH

Seitenzahl

368

Maße (L/B/H)

25,2/17,9/2,7 cm

Gewicht

666 g

Auflage

1. Auflage

Sprache

Englisch

ISBN

978-3-527-34925-8

Herstelleradresse

Wiley-VCH GmbH
Boschstraße 12
69469 Weinheim
DE

Email: [email protected]

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  • Produktbild: Next-Generation Electrochromic Devices
  • About the Author ix

    Preface xi

    Acknowledgments xiii

    1 Introduction 1

    1.1 Electrochromism: A Brief Note on the History and Recent Evolution 1

    Part I Materials 7

    2 Electrochromic Materials 9

    2.1 Inorganic Electrochromic Materials 11

    2.1.1 Transition Metal Oxide Cathodic Materials 12

    2.1.2 Transition Metal Oxide Anodic Materials 23

    2.1.3 Anodic and Cathodic - Transition Metal Oxide Materials: V 2 O 5 28

    2.2 2D Materials 31

    2.2.1 2D Transitional Metal Oxides 32

    2.2.2 Graphene 35

    2.3 Organic Electrochromic Materials 36

    2.3.1 Prussian Blue 36

    2.3.2 Viologens: Small Molecules, Polyviologens, and Hybrid Composite Materials 38

    2.3.3 Semiconducting Polymers 45

    3 Mixed Ionic and Electronic Conductors 55

    3.1 Semiconducting Polymers and Small Molecules 57

    3.2 Structure-Property Relationship and Charge Transport in Disordered Organic Materials 62

    3.3 Potential Impact of Mixed Conductors on the Design of New EC and Multifunctional Devices 65

    4 Electrolytes 67

    4.1 Liquid Electrolytes 68

    4.2 Polymer Electrolytes: From Gel to Solid Polymers 69

    4.2.1 Ionic Conductivity and Transport Properties in Polymer Electrolytes 81

    4.3 Inorganic Electrolytes 85

    5 Electrodes 89

    5.1 Transparent and Conducting Oxides 89

    5.2 Carbon-Based Electrode Materials 91

    5.3 Metal Nanowires and Metal Grids 93

    6 Critical Material Issues 99

    Part II Devices 105

    7 Device Structure: The Key Role of the Interfaces in the Device Design 107

    7.1 Electrochromic Devices 108

    7.1.1 All-Solid-State Double-Substrate Electrochromic Device 110

    7.1.2 Monolithic Single-Substrate Electrochromic Device 116

    7.2 Electrochromic Multifunctional Devices 121

    7.2.1 Photoelectrochromic and Photovoltachromic: Device Architectures 122

    7.2.1.1 Power Supply of Photoelectrochromic Devices: Semitransparent Silicon, DSSC, Polymers, and Perovskite PV Cell 128

    7.2.2 Electrochromic and Electroluminescent Devices: ECOLEDs and ECLECs 140

    7.2.2.1 Electroluminescence, Electrofluorescence, and Electrochromism: Multifunctional Devices Based on Thereof 151

    7.2.3 Electrochromic Energy Storage Devices 156

    7.2.4 Self-Rechargeable Electrochromic Transparent Battery and Self-Powered Photovoltaic Electrochromic Energy Storage Devices 163

    8 Thin-Film Processing Technologies 169

    8.1 Chemical Deposition 170

    8.1.1 Spin Coating, Dip Coating, Spray Coating, and Inkjet Printing 170

    8.1.2 Sol-Gel Method 172

    8.1.3 Electrochemical Deposition 173

    8.1.4 Langmuir-Blodgett Film Deposition 174

    8.1.5 Chemical Vapor Deposition 175

    8.2 Physical Depositions 176

    8.2.1 Thermal and Electron-Beam Evaporation 177

    8.2.2 Sputtering Deposition 178

    8.2.3 Pulsed Laser Deposition 178

    8.2.4 Molecular Beam Epitaxy 179

    9 Analysis of Device Performance 181

    9.1 Optical Spectroscopy 182

    9.1.1 UV-Vis Spectroscopy and Optical Properties 182

    9.1.2 Infrared Spectroscopy 186

    9.2 Electrochemical Analysis 187

    9.2.1 Cyclic Voltammetry 188

    9.2.2 Chronoamperometry 194

    9.2.3 Electrochemical Impedance Spectroscopy: Interface Properties and Ion Diffusion Constants 196

    9.2.4 Cyclic Stability and Long-Term Durability 199

    9.3 Chemical and Physical Methods for Electrochromism and Analysis of Material Properties 209

    9.3.1 X-Ray Photoemission Spectroscopy 210

    9.3.2 FTIR and Raman Spectroscopy 214

    9.3.3 Nuclear Magnetic Resonance Spectroscopy 216

    9.3.4 X-Ray Diffraction Analysis 218

    9.4 Characterization of Mixed Ionic and Electronic Conduction Materials 222

    9.4.1 Direct Measurement of Ion Mobility in OMIECs 225

    Part III Scale-up, Energy and Environment, and Next-generation Technologies 231

    10 Construction of Smart Windows: From Laboratory to Industry Scale 233

    10.1 Manufacturing Processes: Materials and Deposition Techniques 234

    10.2 Scale-Up Procedures: Electrochromic Windows and Large-Area Photovoltaic Modules 248

    10.3 Laminated Smart Windows and Adhesive Electrochromic Smart Films 261

    11 Energy-Efficient Electrochromic Glazings for Green Buildings 263

    11.1 Energy Demand and Consumption in Buildings: Energy Saving of Electrochromic Glazings 267

    11.2 Effect of Electrochromic Glazings on Visual Comfort: Usable UDI and Dgi 270

    12 Emerging and Next-Generation Technologies for Fabrication of Dynamic Tintable Windows 273

    12.1 Smart Photoelectrochromic and Thermochromic Windows: Green Technologies Toward More Sustainable Buildings 273

    12.2 Emerging and Next-Generation Technologies 283

    12.3 The New Era of Artificial Intelligence: Toward Immersive Reality and Invisible Technologies 291

    References 299

    Index 337