A variety of industrial processes rely on organometallic chemistry,
and its applications are prominent in natural product synthesis,
pharmaceuticals, polymers, and materials science. Fully updated and
expanded to reflect recent advances, the Fifth Edition of the
classic text provides students and professional chemists with a
comprehensive introduction to the principles and general properties
of organometallic compounds and includes practical information on
reaction mechanisms and contemporary applications. With an
increased focus on organic synthesis applications, nanoparticle
science, and green chemistry, the new edition brings the entire
subject up to date.
Fully updated and expanded to reflect recent advances, this fifth
edition of the classic text provides students and professional
chemists with a comprehensive introduction to the principles and
general properties of organometallic compounds, as well as
including practical information on reaction mechanisms and detailed
descriptions of contemporary applications. With increased focus on
organic synthesis applications, nanoparticle science, and green
chemistry, the fifth edition brings the entire content up to date.
"At the same time, that same model guarantees that it will still be one of the primary choices of the next generation of organometallic chemists and readers with interests in organometallic chemistry. " (ACS' Organometallics Journal, 1 December 2010)
Robert H. Crabtree, PhD, is a professor in the Department of Chemistry at Yale University.
Inhaltsangabe
Acknowledgment
Preface
List of Abbreviations
1. Introduction
1.1 Why Study Organometallic Chemistry?
1.2 Coordination Chemistry
1.3 Werner Complexes
1.4 The Trans Effect
1.5 Soft versus Hard Ligands
1.6 The Crystal Field
1.7 The Ligand Field
1.8 Back Bonding
1.9 Electroneutrality
1.10 Types of Ligand
2. General Properties of Organometallic Complexes
2.1 The 18-Electron Rule
2.2 Limitations of the 18-Electron Rule
2.3 Electron Counting in Reactions
2.4 Oxidation State
2.5 Coordination Number and Geometry
2.6 Effects of Complexation
2.7 Differences between Metals
2.8 Supramolecular Chemistry
3. Metal Alkyls, Aryls, and Hydrides and Related s-Bonded Ligands
3.1 Transition Metal Alkyls and Aryls
3.2 Related s-Bonded Ligands
3.3 Metal Hydride Complexes
3.4 ÃComplexes
3.5 Bond Strengths for Classical Ã-Bonding Ligands
4. Carbonyls, Phosphine Complexes, and Ligand Substitution Reactions
4.1 Metal Complexes of CO, RNC, CS, and NO
4.2 Phosphines and Related Ligands
4.3 Dissociative Substitution
4.4 Associative Substitution
4.5 Redox Effects, The I Mechanism, and Rearrangements in Substitution
4.6 Photochemical Substitution
4.7 Steric and Solvent Effects in Substitution
5. Complexes of p-Bound Ligands
5.1 Alkene and Alkyne Complexes
5.2 Allyl Complexes
5.3 Diene Complexes
5.4 Cyclopentadienyl Complexes
5.5 Arenes and Other Alicyclic Ligands
5.6 Metalacycles and Isolobal Replacement
5.7 Stability of Polyene and Polyenyl Complexes
6. Oxidative Addition and Reductive Elimination
6.1 Concerted Additions
6.2 SN2 Reactions
6.3 Radical Mechanisms
6.4 Ionic Mechanisms
6.5 Reductive Elimination
6.6 s-Bond Metathesis
6.7 Oxidative Coupling and Reductive Fragmentation
7. Insertion and Elimination
7.1 Reactions Involving CO
7.2 Insertions Involving Alkenes
7.3 Other Insertions
7.4 a, b, g, and d Elimination
8. Nucleophilic and Electrophilic Addition and Abstraction
8.1 Nucleophilic Addition to CO
8.2 Nucleophilic Addition to Polyene and Polyenyl Ligands
8.3 Nucleophilic Abstraction in Hydrides, Alkyls, and Acyls
8.4 Electrophilic Addition
8.5 Electrophilic Abstraction of Alkyl Groups
8.6 Single-Electron Transfer Pathways
8.7 Reactions of Organic Free Radicals with Metal Complexes
9. Homogeneous Catalysis
9.1 Alkene Isomerization
9.2 Alkene Hydrogenation
9.3 Alkene Hydroformylation
9.4 Hydrocyanation of Butadiene
9.5 Alkene Hydrosilylation and Hydroboration
9.6 Coupling Reactions
9.7 Organometallic "Oxidase" Reactions
9.8 Surface and Supported Organometallic Catalysis
10. Physical Methods in Organometallic Chemistry
10.1 Isolation
10.2 1H NMR Spectroscopy
10.3 13C NMR Spectroscopy
10.4 31P NMR Spectroscopy
10.5 Dynamic NMR
10.6 Spin Saturation Transfer
10.7 T1 and the Nuclear Overhauser Effect
10.8 Isotopic Perturbation of Resonance
10.9 IR Spectroscopy
10.10 Crystallography
10.11 Other Methods
11. Metal-Ligand Multiple Bonds
11.1 Carbenes
11.2 Carbynes
11.3 Bridging Carbenes and Carbynes
11.4 N-Heterocyclic Carbenes
11.5 Multiple Bonds to Heteroatoms
12. Applications of Organometallic Chemistry
12.1 Alkene Metathesis
12.2 Dimerization, Oligomerization, and Polymerization of Alkenes
12.3 Activation of CO and CO2
12.4 C-H Activation
12.5 Organometallic Materials and Polymers
13. Clusters, Nanoparticles, Materials, and Surfaces
13.1 Cluster Structures
13.2 Structures
13.3 The Isolobal Analogy
13.4 Nanoparticles
13.5 Giant Molecules
13.6 Organometallic Materials
14. Applications to Organic Synthesis
14.1 Catalyzed Carbon-Carbon and Carbon-Heteroatom Bond Formation
14.2 Metathesis
14.3 Rhodium Carbenes in Cyclopropanation and C-H Insertion
14.4 Hydrogenation and Related Reactions
14.5 Carbonylation
14.6 Oxidation
14.7 C?H Activation
14.8 Click Chemistry
14.9 Noncatalytic Reactions
15 Paramagnetic, High-Oxidation-State, and High-Coordination? Number Complexes
