Hydrocarbon Thermal Isomerizations summarizes rearrangements which
are induced by heating neutral hydrocarbons under non-catalytic
conditions in the vapor phase or in non-polar solution. This
subject has attracted the interest of mechanistic organic chemists
and theorists in the last quarter century because it is one of the
few fields workable by state of the art techniques of both camps.
This work collects together most of the crucial rate and
stereochemical data in a single volume, along with a critical
analysis of each of these reactions.
Unlike reviews or other books in this area that focus on reaction
types, e.g.. electrocyclic reactions, or Claisen rearrangements,
this volume is organized like the Chemical Abstracts Formula Index,
but with an important exception: all of the relevant derivatives of
each parent compound are discussed with the parent and not in their
logical formula index positions. As it is not always obvious what
is a parent material and what is a derivative, detailed
cross-references are included throughout.
An important aspect of this edition is the inclusion of
calculational results that provide insight, often more than was
anticipated, into these relatively simple reactions
·Energetics of thermal isomerization reactions
·Stereochemistry of thermal isomerization reactions
·Organization to facilitate and integrate global analyses
·Comparison of experimental and theoretical results